Black★Rock Shooter OVA.Mato Kuroi makes friends with a girl named Yomi Takanashi who recently moved to the town. Mato quickly joins the basketball club, which incites Yomi to join the volleyball club since both clubs practice at the same time in the gymnasium. The two spend much time together over the following year, and during one outing Mato gives Yomi the same phone charm she has. In their second year of junior high, they end up in different classes, reducing the amount of time they can spend together. Furthermore, Yomi starts to become jealous of Mato hanging around her basketball club manager and classmate, Yuu Kotari. When Yomi seemingly disappears, Mato becomes concerned when she does not show up at school the next day or respond to her text messages. Mato becomes further depressed when she receives word that Yomi has been reported missing and is asked about her whereabouts by two detectives. One day, Mato receives a blank text message from Yomi and goes to her favorite spot in town where she finds the phone charm she gave her. The charm starts to glow and transports her to a strange world where she meets Black Rock Shooter, a mysterious girl with a blazing blue eye. As Mato tries to find Yomi, she merges with Black Rock Shooter and duels Yomi, who was possessed by an evil being called Dead Master. As the possessed Yomi is about to fall to her death, Black Rock Shooter saves Yomi from falling, and embraces her, causing Yomi's body to be free from Dead Master. The events of their lengthy battle are dispersed throughout the anime. Yomi and Mato return to their normal lives, but Yuu begins to act strangely.